N -(1-Allyl-1 H -indazol-5-yl)-4-methoxybenzenesulfonamide hemihydrate
In the title compound, C17H17N3O3.0.5H2O, the indazole system makes a dihedral angle of 46.19 (8)° with the plane through the benzene ring and is nearly perpendicular to the allyl group, as indicated by the dihedral angle of 81.2 (3)°. In the crystal, the water molecule, disordered over two sites re...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-10, Vol.69 (10), p.o1589-o1590 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | In the title compound, C17H17N3O3.0.5H2O, the indazole system makes a dihedral angle of 46.19 (8)° with the plane through the benzene ring and is nearly perpendicular to the allyl group, as indicated by the dihedral angle of 81.2 (3)°. In the crystal, the water molecule, disordered over two sites related by an inversion center, forms O-H...N bridges between indazole N atoms of two sulfonamide molecules. It is also connected via N-H...O interaction to the third sulfonamide molecule; however, due to the water molecule disorder, only every second molecule of sulfonamide participates in this interaction. This missing interaction results in a slight disorder of the sulfonamide S,O and N atoms which are split over two sites with half occupancy. With the help of C-H...O hydrogen bonds, the molecules are further connected into a three-dimensional network. |
---|---|
ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536813025543 |