Crystal structure of bis-[4-(all-yloxy)- N '-(but-2-en-1-yl-idene)benzohydrazidato]nickel(II)

In the title complex, [Ni(C H N O ) ], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged , chelating ligands in a configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-05, Vol.79 (Pt 5), p.465-468
Hauptverfasser: Khan, Sultana Shakila, Howlader, Md Belayet Hossain, Sheikh, Md Chanmiya, Miyatake, Ryuta, Zangrando, Ennio
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Sprache:eng
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Zusammenfassung:In the title complex, [Ni(C H N O ) ], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged , chelating ligands in a configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole mol-ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)°. The crystal packing is supported by C-H⋯π and C-H⋯O inter-actions that form a di-periodic layered network.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989023002918