Crystal structure of bis-[4-(all-yloxy)- N '-(but-2-en-1-yl-idene)benzohydrazidato]nickel(II)
In the title complex, [Ni(C H N O ) ], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged , chelating ligands in a configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-05, Vol.79 (Pt 5), p.465-468 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | In the title complex, [Ni(C
H
N
O
)
], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged
,
chelating ligands in a
configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole mol-ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)°. The crystal packing is supported by C-H⋯π and C-H⋯O inter-actions that form a di-periodic layered network. |
---|---|
ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989023002918 |