Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ 2 C 1 , N ](picolinato-κ 2 N , O )iridium(III) chloroform monosolvate
In the title complex, [Ir(C12H8F2N)2(C6H4NO2)]·CHCl3, two similar molecules of each component comprise the asymmetric unit. The independent complex molecules are linked by intermolecular π–π interactions [centroid–centroid distance = 3.830 (4)...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-09, Vol.67 (9), p.m1199-m1200 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title complex, [Ir(C12H8F2N)2(C6H4NO2)]·CHCl3, two similar molecules of each component comprise the asymmetric unit. The independent complex molecules are linked by intermolecular π–π interactions [centroid–centroid distance = 3.830 (4) Å]. The IrIII ion adopts a distorted octahedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536811030856 |