4,6-Di- tert -butyl-2-{( E )-[4-(dimethylamino)phenylimino]methyl}phenol

4,6-Di- tert -butyl-2-{( E )-[4-(dimethylamino)phenylimino]methyl}phenol

The title compound, C 23 H 32 N 2 O, adopts an E conformation about the C=N bond. The dihedral angle between the aromatic rings is 25.39 (14)°. One of the tert -butyl groups has rotational disorder, with site occupancies of 0.716 (3) and 0.284 (3). An intramolecular O—H...N hydrogen bond is present,...

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Veröffentlicht in:IUCrData 2017-03, Vol.2 (3), p.x170396, Article x170396
Hauptverfasser: Rani, C. Vidya, Mitu, L., Chakkaravarthi, G., Rajagopal, G.
Format: Artikel
Sprache:eng
Schlagworte:
crystal structure
hydrogen bonding
Schiff base
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Zusammenfassung:The title compound, C 23 H 32 N 2 O, adopts an E conformation about the C=N bond. The dihedral angle between the aromatic rings is 25.39 (14)°. One of the tert -butyl groups has rotational disorder, with site occupancies of 0.716 (3) and 0.284 (3). An intramolecular O—H...N hydrogen bond is present, forming an S(6) ring motif.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314617003960