Recent applications of the (TMS)3SiH radical-based reagent

This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allo...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2012-01, Vol.17 (1), p.527-555
Hauptverfasser:	Chatgilialoglu, Chryssostomos, Lalevée, Jacques
Format:	Artikel
Sprache:	eng
Schlagworte:	hydrosilylation Indicators and Reagents - chemistry Models, Chemical photopolymerization Polymerization radical reactions Reducing Agents - chemistry reduction Review Silanes - chemical synthesis Silanes - chemistry silyl radical tris(trimethylsilyl)silane
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Beschreibung
Zusammenfassung:	This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allows reactions to be carried out under mild conditions with excellent yields of products and remarkable chemo-, regio-, and stereoselectivity. The strategic role of (TMS)(3)SiH in polymerization is underlined with emphasis on the photo-induced radical polymerization of olefins and photo-promoted cationic polymerization of epoxides.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules17010527