The Growth Mechanism, Luminescence, and Lasing of Polyhedral ZnO Microcrystals with Whispering-Gallery Modes

This work studies the features of the formation of isometric polyhedral ZnO microcrystals that provide stimulated emission and whispering-gallery-mode (WGM) lasing in the near-UV range. For this purpose, the growth stages of such crystals in the process of gas-transport synthesis and the luminescent properties of the structures obtained at each stage were investigated. It was shown that the growth of laser microcrystals begins with the formation of microspheroids with thin ZnO shells. Such spheroids exhibit mainly white luminescence with a small contribution of near-UV emission. Increasing the synthesis duration results in thickening and faceting of the spheroid shells, as well as a decrease in the contribution of the yellow–red component to the luminescence spectrum. At the same time, ZnO microcrystallites nucleate and grow inside the spheroids, using as a material the remains of a liquid zinc drop and oxygen entering the spheroids through their shells. Such growth conditions allow them to take on an equilibrium polyhedral shape. Eventually, upon destruction of the spheroid shell, a polyhedral ZnO microcrystal supporting WGMs is observed.