Bis[2-(3-chlorobenzylidene)propanoato-κ 2 O , O ′]diethyltin(IV)
In the molecule of the title compound, [Sn(C2H5)2(C10H8ClO2)2], the Sn atom is six-coordinated in a distorted tetragonal-bipyramidal configuration by four O atoms in the equatorial plane and two C atoms in the axial positions. Intramolecular C-H...O hydrogen bonds result in the formation of two plan...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-07, Vol.64 (7), p.m946-m947 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the molecule of the title compound, [Sn(C2H5)2(C10H8ClO2)2], the Sn atom is six-coordinated in a distorted tetragonal-bipyramidal configuration by four O atoms in the equatorial plane and two C atoms in the axial positions. Intramolecular C-H...O hydrogen bonds result in the formation of two planar and two non-planar five-membered rings; the latter adopt envelope conformations. There are weak π-π interactions between aromatic rings, with centroid-to-centroid distances of 3.796 (2) and 4.171 (2) Å. There is also a single C-Cl...π interaction [C-Cl = 1.740 (4), Cl...π = 3.795 (2) C...π = 3.697 (4) Åand C-Cl...p =73.45 (11)°]. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536808018321 |