Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetox...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2015-12, Vol.20 (12), p.22635-22644
Hauptverfasser:	Jobin-Des Lauriers, Antoine, Legault, Claude Y
Format:	Artikel
Sprache:	eng
Schlagworte:	(diacetoxyiodo)arenes Aromatic compounds Benzene Derivatives - chemistry Computer applications Equilibrium Hydrocarbons hypervalent iodine Iodine Iodine Compounds - chemistry Lewis acid Ligands metathesis Organic chemistry Oxidation Oxidation-Reduction Reagents Thermodynamics
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Beschreibung
Zusammenfassung:	The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules201219874