Sb2S3-templated synthesis of sulfur-doped Sb-N-C with hierarchical architecture and high metal loading for H2O2 electrosynthesis

Selective two-electron (2e − ) oxygen reduction reaction (ORR) offers great opportunities for hydrogen peroxide (H 2 O 2 ) electrosynthesis and its widespread employment depends on identifying cost-effective catalysts with high activity and selectivity. Main-group metal and nitrogen coordinated carbons (M-N-Cs) are promising but remain largely underexplored due to the low metal-atom density and the lack of understanding in the structure-property correlation. Here, we report using a nanoarchitectured Sb 2 S 3 template to synthesize high-density (10.32 wt%) antimony (Sb) single atoms on nitrogen- and sulfur-codoped carbon nanofibers (Sb-NSCF), which exhibits both high selectivity (97.2%) and mass activity (114.9 A g −1 at 0.65 V) toward the 2e − ORR in alkaline electrolyte. Further, when evaluated with a practical flow cell, Sb-NSCF shows a high production rate of 7.46 mol g catalyst −1 h −1 with negligible loss in activity and selectivity in a 75-h continuous electrolysis. Density functional theory calculations demonstrate that the coordination configuration and the S dopants synergistically contribute to the enhanced 2e − ORR activity and selectivity of the Sb-N 4 moieties. Selective two-electron oxygen reduction reaction is critical electrochemical process for H 2 O 2 electrosynthesis. Here, the authors develop a Sb 2 S 3 -templated strategy to fabricate high-density atomic dispersion of Sb on N,S-codoped hollow carbon nanofiber substrate, which facilitate with the improved selectivity, catalytic mass activity and production rate of H 2 O 2 .