CuCr2O4@rGO Nanocomposites as High-Performance Cathode Catalyst for Rechargeable Lithium–Oxygen Batteries
Rechargeable lithium–oxygen batteries have been considered as a promising energy storage technology because of their ultra-high theoretical energy densities which are comparable to gasoline. In order to improve the electrochemical properties of lithium–oxygen batteries (LOBs), especially the cycling...
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Veröffentlicht in: | Nano-micro letters 2018, Vol.10 (2), p.1-10, Article 22 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Rechargeable lithium–oxygen batteries have been considered as a promising energy storage technology because of their ultra-high theoretical energy densities which are comparable to gasoline. In order to improve the electrochemical properties of lithium–oxygen batteries (LOBs), especially the cycling performance, a high-efficiency cathode catalyst is the most important component. Hence, we aim to demonstrate that CuCr
2
O
4
@rGO (CCO@rGO) nanocomposites, which are synthesized using a facile hydrothermal method and followed by a series of calcination processes, are an effective cathode catalyst. The obtained CCO@rGO nanocomposites which served as the cathode catalyst of the LOBs exhibited an outstanding cycling performance for over 100 cycles with a fixed capacity of 1000 mAh g
−1
at a current density of 200 mA g
−1
. The enhanced properties were attributed to the synergistic effect between the high catalytic efficiency of the spinel-structured CCO nanoparticles, the high specific surface area, and high conductivity of the rGO. |
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ISSN: | 2311-6706 2150-5551 |
DOI: | 10.1007/s40820-017-0175-z |