Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents

Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents

In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds, as well as new Pd-catalyzed cross-coupling reacti...

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Veröffentlicht in:Beilstein journal of organic chemistry 2011-09, Vol.7 (1), p.1261-1277
Hauptverfasser: Knochel, Paul, Schade, Matthias A, Bernhardt, Sebastian, Manolikakes, Georg, Metzger, Albrecht, Piller, Fabian M, Rohbogner, Christoph J, Mosrin, Marc
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
cross-coupling
heterocycles
insertion
metalation
organomagnesium
organozinc
Review
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Beschreibung
Zusammenfassung:In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds, as well as new Pd-catalyzed cross-coupling reactions, are reported herein. Experimental details are given for the most important reactions in the Supporting Information File 1 of this article.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.7.147