Enhanced Dichroism of Polarizing Composite Films by Embedding Sepiolite

The present study investigated the use of fibrous nanoparticle-filled polarizing films. Sepiolites were selected as nanoparticles and incorporated into a PVA–iodine complex. The resulting nanocomposite film was elongated and dyed with iodine. Various properties of the nanocomposite polarizing films, including thermal, morphological, optical, and rheological features, were experimentally analyzed. The study demonstrated that an increase in sepiolite loading was accompanied by an enhancement in both the mechanical and viscoelastic properties. In particular, the incorporation of nanoparticles led to an increase in birefringence and the degree of polarization. This was attributed to the alteration of the internal structure of the PVA film caused by the embedded sepiolites. The thermal analysis showed that the composite film with a higher content of sepiolites exhibited higher crystallinity and a higher melting temperature.