1-[2-(4-Nitro-phen-yl)-5-(5-phenyl-1,2-oxazol-3-yl)-1,2,3,4-tetra-hydro-quinolin-4-yl]pyrrolidin-2-one monohydrate
The title compound, C(28)H(24)N(4)O(4)·H(2)O, crystallizes with two organic mol-ecules and two solvent water mol-ecules in the asymmetric unit. The most obvious difference between the mol-ecules is the torsion angles between the isoxazole ring and the benzene and phenyl rings [47.0 (2)/56.4 (2) and...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-01, Vol.67 (Pt 1), p.o175-o176 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title compound, C(28)H(24)N(4)O(4)·H(2)O, crystallizes with two organic mol-ecules and two solvent water mol-ecules in the asymmetric unit. The most obvious difference between the mol-ecules is the torsion angles between the isoxazole ring and the benzene and phenyl rings [47.0 (2)/56.4 (2) and 33.3 (2)/11.0 (2)°, respectively]. Another important difference is observed in the rotation of the nitro group with respect to the phenyl groups [3.5 (6) and 31.1 (6)°]. The pyrrolidinone fragment is cis oriented with respect to the 4-nitro-phenyl fragment. In the crystal, mol-ecules are linked into centrosymmetric R(4) (2)(8) and R(4) (4)(20) motifs by O-H⋯O and N-H⋯O inter-actions. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810052463 |