(Acetyl-acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate

In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand....

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (Pt 9), p.m1062-m1063
Hauptverfasser: Janani, Halimeh, Rezvani, Ali Reza, Rostami-Charati, Faramarz, Makha, Mohamed, Skelton, Brian W
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Sprache:eng
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Zusammenfassung:In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol-ecules. There are also hydrogen bonds between both the water mol-ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810030163