(Acetyl-acetonato)(dicyanamido)(1,10-phenanthroline)copper(II) dihydrate
In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand....
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (Pt 9), p.m1062-m1063 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title compound, [Cu(C(5)H(7)O(2))(C(2)N(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is five-coordinated in a square-pyramidal geometry with two acetyl-acetonate O and two phenanthroline N atoms forming the base. The apical position is occupied by the central N atom of the dicyanamide ligand. The dicyanamide N atoms are each involved in hydrogen bonds to water mol-ecules. There are also hydrogen bonds between both the water mol-ecules and their centrosymmetric pairs, creating a hydrogen-bonded chain along the b-axis direction. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810030163 |