Toward Practical Single‐Molecule/Atom Switches

Electronic switches have been considered to be one of the most important components of contemporary electronic circuits for processing and storing digital information. Fabricating functional devices with building blocks of atomic/molecular switches can greatly promote the minimization of the devices and meet the requirement of high integration. This review highlights key developments in the fabrication and application of molecular switching devices. This overview offers valuable insights into the switching mechanisms under various stimuli, emphasizing structural and energy state changes in the core molecules. Beyond the molecular switches, typical individual metal atomic switches are further introduced. A critical discussion of the main challenges for realizing and developing practical molecular/atomic switches is provided. These analyses and summaries will contribute to a comprehensive understanding of the switch mechanisms, providing guidance for the rational design of functional nanoswitch devices toward practical applications. This review highlights the key developments in the fabrication and application of molecular/atomic switching devices, aiming to provide a comprehensive understanding of the working principles and elucidate the factors that influence their performance. A critical discussion of the main challenges for realizing and developing practical molecular/atomic switches is provided as well.