Crystal structure of N′-[2-(benzo[d]thiazol-2-yl)acetyl]benzohydrazide, an achiral compound crystallizing in space group P1 with Z = 1

In the molecule of the title compound, C16H13N3O2S, one hydrazinic nitrogen atom is essentially planar, but the other is slightly pyramidalized. The torsion angle about the hydrazinic bond is 66.44 (15)°. Both hydrazinic hydrogen atoms lie antiperiplanar to the oxygen of the adjacent carbonyl group....

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2021-09, Vol.77 (9), p.891-894
Hauptverfasser: Rasha A. Azzam, Galal H. Elgemeie, Mona M. Seif, Peter G. Jones
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Sprache:eng
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Zusammenfassung:In the molecule of the title compound, C16H13N3O2S, one hydrazinic nitrogen atom is essentially planar, but the other is slightly pyramidalized. The torsion angle about the hydrazinic bond is 66.44 (15)°. Both hydrazinic hydrogen atoms lie antiperiplanar to the oxygen of the adjacent carbonyl group. The molecular packing is a layer structure determined by two classical hydrogen bonds, N—H...O=C and N—H...Nthiazole. The space group is P1 with Z = 1, which is unusual for an achiral organic compound.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989021007672