( E )- N -(1 H -Pyrrol-2-ylmethylidene)-2-{[( E )-(1 H -pyrrol-2-ylmethylidene)amino]methyl}aniline
The title salophene-type compound, C 17 H 16 N 4 , crystallizes with two independent molecules ( A and B ) in the asymmetric unit. Both (pyrrol-2-yl)methanimine groups have an extended conformation, and an E conformation about the C=N bonds. The pyrrole rings are inclined to the aminobenzylamine rin...
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Veröffentlicht in: | IUCrData 2017-04, Vol.2 (4), p.x170540, Article x170540 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title salophene-type compound, C
17
H
16
N
4
, crystallizes with two independent molecules (
A
and
B
) in the asymmetric unit. Both (pyrrol-2-yl)methanimine groups have an extended conformation, and an
E
conformation about the C=N bonds. The pyrrole rings are inclined to the aminobenzylamine ring by 43.7 (3) and 78.9 (2)° in molecule
A
, and by 46.8 (3) and 79.3 (3)° in molecule
B
, while the pyrrole rings are inclined to one another by 58.9 (3) and 59.9 (3)° in molecules
A
and
B
, respectively. In the crystal, molecules are linked by N—H...N hydrogen bonds, forming chains propagating along the
a
-axis direction. The chains are linked by C—H...π interactions, forming a three-dimensional supramolecular structure. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314617005405 |