( E )- N -(1 H -Pyrrol-2-ylmethylidene)-2-{[( E )-(1 H -pyrrol-2-ylmethylidene)amino]methyl}aniline

The title salophene-type compound, C 17 H 16 N 4 , crystallizes with two independent molecules ( A and B ) in the asymmetric unit. Both (pyrrol-2-yl)methanimine groups have an extended conformation, and an E conformation about the C=N bonds. The pyrrole rings are inclined to the aminobenzylamine rin...

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Veröffentlicht in:IUCrData 2017-04, Vol.2 (4), p.x170540, Article x170540
Hauptverfasser: Raghuvarman, B., Gayathri, Jayagopi, Selvan, Kumar Sangeetha, Sugumar, P., Ponnuswamy, M. N.
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Sprache:eng
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Zusammenfassung:The title salophene-type compound, C 17 H 16 N 4 , crystallizes with two independent molecules ( A and B ) in the asymmetric unit. Both (pyrrol-2-yl)methanimine groups have an extended conformation, and an E conformation about the C=N bonds. The pyrrole rings are inclined to the aminobenzylamine ring by 43.7 (3) and 78.9 (2)° in molecule A , and by 46.8 (3) and 79.3 (3)° in molecule B , while the pyrrole rings are inclined to one another by 58.9 (3) and 59.9 (3)° in molecules A and B , respectively. In the crystal, molecules are linked by N—H...N hydrogen bonds, forming chains propagating along the a -axis direction. The chains are linked by C—H...π interactions, forming a three-dimensional supramolecular structure.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314617005405