2-(4-Chloro-2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole-3-carbaldehyde

In the title compound, C25H15ClN2O6S, the carbazole ring system is essentially planar, with a maximum deviation of 0.152 (3) Å for the C atom to which the 4-chloro-2-nitrophenyl ring is attached. Its mean plane is almost orthogonal to the phenylsulfonyl and nitrophenyl rings, making dihedral angles...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-09, Vol.69 (9), p.o1420-o1421
Hauptverfasser: S. Gopinath, K. Sethusankar, Bose Muthu Ramalingam, Arasambattu K. Mohanakrishnan
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C25H15ClN2O6S, the carbazole ring system is essentially planar, with a maximum deviation of 0.152 (3) Å for the C atom to which the 4-chloro-2-nitrophenyl ring is attached. Its mean plane is almost orthogonal to the phenylsulfonyl and nitrophenyl rings, making dihedral angles of 82.64 (14) and 79.89 (13)°, respectively. The N atom of the nitro group deviates by 0.032 (3) Å from the benzene ring to which it is attached. The molecular structure features intramolecular O-H...O and C-H...O hydrogen bonds, which generate three S(6) ring motifs. In the crystal, molecules are linked by C-H...O hydrogen bonds, which generate C(6) and C(9) chains running in the [100] and [010] directions, respectively, forming a two-dimensional network lying parallel to (001). There are also R43(28) supramolecular graph-set ring motifs enclosed within these networks.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813022253