Oxido[N-(2-oxidobenzyl-idene-κO)leucinato-κ²N,O](1,10-phenanthroline-κ²N,N')vanadium(IV)

Oxido[N-(2-oxidobenzyl-idene-κO)leucinato-κ²N,O](1,10-phenanthroline-κ²N,N')vanadium(IV)

In the title V(IV) complex, [VO(C₁₃H₁₅NO₃)(C₁₂H₈N₂)], the oxidovanadium cation is N,N'-chelated by a 1-10-phenanthroline ligand and N,O,O'-chelated by a Schiff base anion in a distorted octa-hedral geometry. Weak inter-molecular C-H⋯O hydrogen bonds occur in the crystal structure which con...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-07, Vol.68 (Pt 7), p.m907-m907
Hauptverfasser: Wang, Cheng-Yuan, Jing, Bu-Qin, Dong, Jian-Fang, Li, Lian-Zhi
Format: Artikel
Sprache:eng
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Metal-Organic Papers
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Zusammenfassung:In the title V(IV) complex, [VO(C₁₃H₁₅NO₃)(C₁₂H₈N₂)], the oxidovanadium cation is N,N'-chelated by a 1-10-phenanthroline ligand and N,O,O'-chelated by a Schiff base anion in a distorted octa-hedral geometry. Weak inter-molecular C-H⋯O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81 ų.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812025391