3-(1-Adamantylamino)-3-methyl-1-phenylquinoline-2,4(1 H ,3 H )-dione
The structure of the title compound, C26H28N2O2, contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)&...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-08, Vol.65 (8), p.o1866-o1866 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The structure of the title compound, C26H28N2O2, contains essentially planar quinoline and benzene rings, the maximum deviations from the best plane being 0.086 (2) and 0.0056 (19) Å, respectively; the dihedral angle between the rings is 82.87 (4)°. The adamantane cage consists of three fused cyclohexane rings in classical chair conformations, with C—C—C angles in the range 107.85 (15)–111.35 (15)°. Enantiomers are linked alternately into chains along the c axis via short N—H...O interactions and further C–H...π interactions stabilize pairs of enantiomers, forming a two-dimensional network. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809026464 |