Virial expansions and augmented van der Waals approach: Application to Lennard-Jones-like Yukawa fluid

We argue that recently proposed [Melnyk et al., Fluid Phase Equilibr., 2009, 279, 1] a criterion to split the pair interaction potential into two parts, one of which is forced to be responsible for excluded volume in the system, results in the expressions for virial coefficients that improve the per...

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Veröffentlicht in:Condensed matter physics 2015-01, Vol.18 (1), p.13501
Hauptverfasser: Trokhymchuk, Melnyk, Nezbeda
Format: Artikel
Sprache:eng
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Zusammenfassung:We argue that recently proposed [Melnyk et al., Fluid Phase Equilibr., 2009, 279, 1] a criterion to split the pair interaction potential into two parts, one of which is forced to be responsible for excluded volume in the system, results in the expressions for virial coefficients that improve the performance of the virial equation of state in general, and at subcritical temperatures, in particular. As an example, application to the Lennard-Jones-like hard-core attractive Yukawa fluid is discussed.
ISSN:1607-324X
DOI:10.5488/CMP.18.13501