Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) μ-oxalato-bis-[n-butyl-tri-chlorido-stannate(IV)]
The Sn(IV) atom in the centrosymmetric anion of the title salt, (C4H7N2)2[Sn2(C4H9)2(C2O4)Cl6], is coordinated in a distorted octa-hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33...
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Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2016-06, Vol.72 (Pt 6), p.858-860 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The Sn(IV) atom in the centrosymmetric anion of the title salt, (C4H7N2)2[Sn2(C4H9)2(C2O4)Cl6], is coordinated in a distorted octa-hedral mode by two O atoms of a bridging oxalate moiety, three Cl atoms and a C atom of an n-butyl group. The latter is disordered over two sets of sites in a 0.66:0.33 occupancy ratio. N-H⋯O and N-H⋯Cl hydrogen bonds involving the 2-methyl-imidazolium cation and neighbouring anions result in the formation of chains extending parallel to [001]. |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989016008434 |