2-[(4-Chloro-benz-yl)sulfan-yl]-4-(2-methyl-prop-yl)-6-(phenyl-sulfan-yl)pyrimidine-5-carbonitrile

In the title compound, C(22)H(20)ClN(3)S(2), the S-bound benzene rings are inclined [dihedral angles = 78.13 (10) and 36.70 (9)°] with respect to the pyrimidine ring. The methyl-propyl group occupies a position normal to the pyrimidine ring [N-C-C-C torsion angle = 92.3 (2)°]. In the crystal, supra-...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-07, Vol.68 (Pt 7), p.o2055-o2056
Hauptverfasser: El-Emam, Ali A, Al-Deeb, Omar A, Al-Turkistani, Abdulghafoor A, Ng, Seik Weng, Tiekink, Edward R T
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Sprache:eng
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Zusammenfassung:In the title compound, C(22)H(20)ClN(3)S(2), the S-bound benzene rings are inclined [dihedral angles = 78.13 (10) and 36.70 (9)°] with respect to the pyrimidine ring. The methyl-propyl group occupies a position normal to the pyrimidine ring [N-C-C-C torsion angle = 92.3 (2)°]. In the crystal, supra-molecular layers are formed in the bc plane, being consolidated by C-H⋯π and π-π inter-actions, the latter between the pyrimidine and S-bound benzene rings [inter-centroid distance = 3.7683 (12) Å].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812025810