Assessment of contamination and origin of metals in mining affected river sediments: A case study of the Aries catchment, Romania

The study presents the current status of contamination with metals (Cu, Cr, Cd, Pb, Ni, Zn, As) and their anthropogenic or natural origin in the sediments of the Aries river basin. Romania, affected by mining activities. The results indicated an enrichment of metals in sediments. Different contamination levels were identified on the Aries river and its tributaries. According to sediment quality guidelines and contamination indices, sediments from the Aries river were found to be highly contaminated with Cd, Cu, As, considerably with Zn and moderately with Pb and Ni. The right-bank tributaries were found to be more contaminated than the left-bank affluents, where only a contamination with As of geogenic origin was identified. The Principal Component Analysis allowed to identify five latent factors (86% total variability) reflecting the anthropogenic and natural origins of metals. Arsenic. Cd and partially Pb were found to have a common anthropogenic origin, different from that of Cu. The statistical approach indicated also the geogenic origin of Pb due to its association with Ca, K, Na, Sr. Chromium and Ni were attributed to natural source following their association with Mn, Fe, Al and Mg, respectively.