8-Phenyl-16-thiapentacyclo[6.6.5.0 1,18 .0 2,7 .0 9,14 ]nonadeca-2,4,6,9,11,13,18-heptaene

In the title compound, C24H18S, the dihedral angles between the phenyl ring and the two benzene rings of the anthracene moiety are 51.92 (9) and 68.24 (9)°, whereas the dihedral angle between the two anthracene benzene rings is 120.13 (9)°. The three non-aromatic six-membered rings are in boat confo...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-07, Vol.69 (7), p.o1165-o1165
Hauptverfasser: Mathew, Eason M., Sithambaresan, M., Unnikrishnan, P. A., Kurup, M. R. Prathapachandra
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C24H18S, the dihedral angles between the phenyl ring and the two benzene rings of the anthracene moiety are 51.92 (9) and 68.24 (9)°, whereas the dihedral angle between the two anthracene benzene rings is 120.13 (9)°. The three non-aromatic six-membered rings are in boat conformations, while the five-membered ring has an envelope conformation on the S atom. In the crystal, there are three C-H...π interactions, which facilitate the packing of the molecules.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813017285