Tetrakis[μ 3 -4-nitro- N -(5-phenyl-1,3,4-oxadiazol-2-yl)benzamidato]tetrakis[methanolsodium(I)]

Tetrakis[μ 3 -4-nitro- N -(5-phenyl-1,3,4-oxadiazol-2-yl)benzamidato]tetrakis[methanolsodium(I)]

In the title compound, [Na4(C15H9N4O4)4(CH3OH)4], the N3O3 environment around the Na+ ion is distorted octahedral. In the unit cell, four Na+ ions are bridged by four Schiff base anions, leading to a tetranuclear complex with -4 symmetry. O—H...N hydrogen bonds between the methanol molecul...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-05, Vol.68 (5), p.m570-m570
Hauptverfasser: Yin, Guo-Jie, Zhang, Qing, Li, Dong
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Na4(C15H9N4O4)4(CH3OH)4], the N3O3 environment around the Na+ ion is distorted octahedral. In the unit cell, four Na+ ions are bridged by four Schiff base anions, leading to a tetranuclear complex with -4 symmetry. O—H...N hydrogen bonds between the methanol molecule and the Schiff base anion stabilize the structural set-up.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812014791