Mixtures of methanol and 2-propanol as a potential fuel for direct alcohol fuel cells

The electrochemical oxidation of methanol, 2-propanol, and their mixtures was investigated on a Pt/C thin film electrode in acid solution. It was confirmed that the oxidation of 2-propanol commences at less positive potentials than that of methanol and exhibits significantly higher oxidation current densities at low potentials. When both methanol and 2-propanol were present in the solution, the onset of the oxidation current was the same as for the oxidation of pure 2-propanol. Although both alcohols inhibit the oxidation reaction of each other to a certain extent, steady-state polarization measurements showed that their mixture provides higher current densities than single alcohols over the entire potential region from the hydrogen region to oxide formation on the Pt surface. This implies that the addition of 2-propanol into the fuel may extend the operational range of direct methanol fuel cells. Isptivana je elektrohemijska oksidacija metanola, 2-propanola i njihovih smesa na tankom filmu Pt/C katalizatora u kiseloj sredini. Potvrdjeno je da oksidacija 2-propanola pocinje na manje pozitivnim potencijalima nego oksidacija metanola i da daje znatno vece gustine struja pri nizim potencijalima. Kada su i metanol i 2-propanol prisutni u rastvoru, struja oksidacije se pojavljuje na istom potencijalu kao u slucaju cistog 2-propanola. Mada oba alkohola inhibiraju oksidaciju onog drugog u izvesnoj meri, stacionarma merenja su pokazala da njihova smesa daje vece gustine struja od pojedinacnih alkohola u celoj oblasti potencijala od vodonicne oblasti pa do formiranja oksida na platini. To ukazuje da se radni opseg gorivog sprega sa metanolom moze povecati dodatkom 2-propanola u gorivo.