Crystal structures, Hirshfeld atom refinements and Hirshfeld surface analyses of tris(4,5-dihydrofuran-2-yl)methylsilane and tris(4,5-dihydrofuran-2-yl)phenylsilane
The title compounds, C 13 H 18 O 3 Si ( 1 ) and C 18 H 20 O 3 Si ( 2 ), represent functionalizable dihydrofuranylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of 1 and 2 display weak intermolecular C—H...O hydrogen-bonding interactions (quantified by Hirshfe...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2020-09, Vol.76 (9), p.1514-1519 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The title compounds, C
13
H
18
O
3
Si (
1
) and C
18
H
20
O
3
Si (
2
), represent functionalizable dihydrofuranylsilanes, which permit substitution by a variety of nucleophiles. The crystal structures of
1
and
2
display weak intermolecular C—H...O hydrogen-bonding interactions (quantified by Hirshfeld surface analysis), leading to a two-dimensional supramolecular network for
1
and a one-dimensional supramolecular network for
2
. The crystal structures of
1
and
2
were refined both on the basis of the independent atom model (IAM) and the Hirshfeld atom refinement (HAR) approach, and the results are comparatively discussed. |
|---|---|
| ISSN: | 2056-9890 2056-9890 |
| DOI: | 10.1107/S2056989020011470 |