3,4-Dicyanophenyl 2,3,4,6-tetra- O -acetyl-α- D -glucopyranoside

The title compound, C22H22N2O10, was prepared by the glycosidation method through nitrite displacement on substituted nitrophthalonitrile. The molecule contains a benzene ring, two nitrile groups and an acetyl-protected d-glucose fragment which adopts a chair conformation. The absolute configuration...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008, Vol.64 (1), p.o63-o63
Hauptverfasser: Bin, Yuejing, Zhao, Fuqun, Zhang, Fushi, Wang, Ru-Ji
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C22H22N2O10, was prepared by the glycosidation method through nitrite displacement on substituted nitrophthalonitrile. The molecule contains a benzene ring, two nitrile groups and an acetyl-protected d-glucose fragment which adopts a chair conformation. The absolute configuration was determined by the use of d-glucose as starting material. All substituents of the protected sugar are in equatorial positions, with the exclusive presence of the α-anomer. The crystal packing is stabilized by C-H...O and C-H...N hydrogen-bonding interactions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807049860