4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)

4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)

The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS, and single-crystal X-ray crystallography....

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Veröffentlicht in:MolBank 2023-06, Vol.2023 (2), p.M1644
Hauptverfasser: Thompson, Katelyn D., Weeks, Nathan J., Balaich, Gary J., Iacono, Scott T.
Format: Artikel
Sprache:eng
Schlagworte:
aryl ether
bisphenol
Conflicts of interest
Crystallography
Molecular structure
NMR
Nuclear magnetic resonance
nucleophilic aromatic substitution
organo-fluorine
pentafluoropyridine
Reagents
Single crystals
Software
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Beschreibung
Zusammenfassung:The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS, and single-crystal X-ray crystallography.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1644