Recent developments in the Reformatsky-Claisen rearrangement

The rearrangement of allyl a-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized s...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2012-11, Vol.17 (12), p.14249-14259
Hauptverfasser:	Ishihara, Jun, Hatakeyama, Susumi
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates - chemical synthesis Acetates - chemistry Acids Allyl Compounds - chemical synthesis Allyl Compounds - chemistry Biological Products - chemical synthesis Biological Products - chemistry Carbon Chemical bonds Chemistry Claisen rearrangement Dust Humans indium Molecular Structure Natural products Reagents Reformatsky reaction Reformatsky-Claisen rearrangement Review Solvents zinc Zinc - chemistry
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Beschreibung
Zusammenfassung:	The rearrangement of allyl a-bromoacetates with Zn dust is known as the Reformatsky-Claisen rearrangement. Whereas the Ireland-Claisen rearrangement has been widely used in the synthesis of a diverse range of natural products, the Zn-mediated Reformatsky-Claisen rearrangement has not been utilized so often. In this article, we will provide an overview of recent advances in the Reformatsky-Claisen rearrangement field, including the In-mediated Reformatsky-Claisen rearrangement we have recently developed.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules171214249