Building durable aqueous K-ion capacitors based on MXene family

Obtaining stable aqueous K-ion capacitors is still challenging due to the cathode materials tended to structurally collapse after long-term cycling during large-radius K-ion insertion/extraction. In this work, three different typical MXene electrodes, i.e., Nb2C, Ti2C, and Ti3C2 were individually in...

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Veröffentlicht in:Nano Research Energy 2022-06, Vol.1 (1), p.e9120002
Hauptverfasser: Liang, Guojin, Li, Xinliang, Wang, Yanbo, Yang, Shuo, Huang, Zhaodong, Yang, Qi, Wang, Donghong, Dong, Binbin, Zhu, Minshen, Zhi, Chunyi
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Sprache:eng
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Zusammenfassung:Obtaining stable aqueous K-ion capacitors is still challenging due to the cathode materials tended to structurally collapse after long-term cycling during large-radius K-ion insertion/extraction. In this work, three different typical MXene electrodes, i.e., Nb2C, Ti2C, and Ti3C2 were individually investigated upon their electrochemical behaviors for potassium-ion (K-ion) storage. All these MXene materials exhibited pseudocapacitive-dominated behaviors, fast kinetics, and durable K-ion storage, delivering superior performance compared with other K-ion host materials. According to the experimental results, it could be ascribed to the intrinsically large interlayer distance for K-ion transport and the superb structural stability of MXene even subjected to long-term potassiation/depotassiation process.
ISSN:2791-0091
2790-8119
DOI:10.26599/NRE.2022.9120002