Translating 2D Director Profile to 3D Topography in a Liquid Crystal Polymer

Morphological properties of surfaces play a key role in natural and man‐made objects. The development of robust methods to fabricate micro/nano surface structures has been a long pursuit. Herein, an approach based on molecular self‐assembling of liquid crystal polymers (LCPs) is presented to directly translate 2D molecular director profiles obtained by a photoalignment procedure into 3D topographies, without involving further multi‐step lithographic processes. The principle of surface deformation from a flat morphology into complex topographies is based on the coupling between electrostatic interactions and the anisotropic flow in LCPs. When activated by an electric field, the LCP melts and is driven by electrohydrodynamic instabilities to connect the electrode plates of a capacitor, inducing topographies governed by the director profile of the LCP. Upon switching off the electric field, the formed structures vitrify as the temperature decreases below the glass transition. When heated, the process is reversible as the formed topographies disappear. By pre‐programming the molecular director a variety of structures could be made with increasing complexity. The height, pitch, and the aspect ratio of the textures are further regulated by the conditions of the applied electric field. The proposed approach will open new opportunities for optical and electrical applications. A technique that stores latent information that can be retrieved repeatedly by subjecting the film to an electrical field is presented. Under the electric field, surfaces morph reversibly from flat to a well‐defined corrugated state, while maintaining its layered molecular organization. Anisotropic polymer flow is generated for this purpose using dielectric energy and directed by an underlying 2D structured monolayer.