fac-Tris(pyridine-2-carboxyl-ato-κN,O)cobalt(III)

fac-Tris(pyridine-2-carboxyl-ato-κN,O)cobalt(III)

In the title compound, [Co(C(6)H(4)NO(2))(3)], the Co(III) ion lies on a threefold rotation axis and is in a distorted octa-hedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxyl-ate ligands. The ligands are coordinated in a chelate fashion, forming...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-11, Vol.67 (Pt 11), p.m1596-m1597
Hauptverfasser: Golenia, Irina A, Boyko, Alexander N, Kotova, Natalia V, Haukka, Matti, Kalibabchuk, Valentina A
Format: Artikel
Sprache:eng
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Metal-Organic Papers
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Zusammenfassung:In the title compound, [Co(C(6)H(4)NO(2))(3)], the Co(III) ion lies on a threefold rotation axis and is in a distorted octa-hedral environment defined by three N and three O donor atoms from three fac-disposed pyridine-2-carboxyl-ate ligands. The ligands are coordinated in a chelate fashion, forming three five-membered rings. In the crystal, translationally related complex molecules are organized into columns along [001] via C-H⋯O hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811043303