Photocatalytic and Electrocatalytic Generation of Hydrogen Peroxide: Principles, Catalyst Design and Performance

Highlights Basic principles of photo- and electro-catalytic hydrogen peroxide generation. Recent progresses on the design, performance and mechanisms of photo- and electro-catalysts for hydrogen peroxide generation. Scientific challenges and prospects of engineering photo- and electro-catalysts for hydrogen peroxide production. Hydrogen peroxide (H 2 O 2 ) is a high-demand organic chemical reagent and has been widely used in various modern industrial applications. Currently, the prominent method for the preparation of H 2 O 2 is the anthraquinone oxidation. Unfortunately, it is not conducive to economic and sustainable development since it is a complex process and involves unfriendly environment and potential hazards. In this context, numerous approaches have been developed to synthesize H 2 O 2 . Among them, photo/electro-catalytic ones are considered as two of the most promising manners for on-site synthesis of H 2 O 2 . These alternatives are sustainable in that only water or O 2 is required. Namely, water oxidation (WOR) or oxygen reduction (ORR) reactions can be further coupled with clean and sustainable energy. For photo/electro-catalytic reactions for H 2 O 2 generation, the design of the catalysts is extremely important and has been extensively conducted with an aim to obtain ultimate catalytic performance. This article overviews the basic principles of WOR and ORR, followed by the summary of recent progresses and achievements on the design and performance of various photo/electro-catalysts for H 2 O 2 generation. The related mechanisms for these approaches are highlighted from theoretical and experimental aspects. Scientific challenges and opportunities of engineering photo/electro-catalysts for H 2 O 2 generation are also outlined and discussed.