Bis(4-benzoyl-3-methyl-1-phenyl-4,5-dihydro-1 H -pyrazol-5-olato-κ 2 O , O ′)(methanol-κ O )dioxidouranium(VI) methanol monosolvate
In the title compound, [U(C 17 H 13 N 2 O 2 ) 2 O 2 (CH 3 OH)]·CH 3 OH, the U VI ion is coordinated by seven O atoms in a distorted pentagonal–bipyramidal geometry with two 3-methyl-1-phenyl-4-benzoyl-4,5-dihydro-1 H -pyrazol-5-olate groups with two O atoms in a bidentate chelating coordination mode...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (4), p.m457-m458 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | In the title compound, [U(C
17
H
13
N
2
O
2
)
2
O
2
(CH
3
OH)]·CH
3
OH, the U
VI
ion is coordinated by seven O atoms in a distorted pentagonal–bipyramidal geometry with two 3-methyl-1-phenyl-4-benzoyl-4,5-dihydro-1
H
-pyrazol-5-olate groups with two O atoms in a bidentate chelating coordination mode and by three O atoms, one of which is from a methanol ligand. The crystal packing can be described by alternating layers of complex molecules along the
a
axis. The structure is stabilized by O—H...N and O—H...O hydrogen bonding and van der Waals interactions. |
---|---|
ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812011075 |