Recent applications of polymer supported organometallic catalysts in organic synthesis

Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2010-09, Vol.15 (9), p.6306-6331
1. Verfasser:	Kann, Nina
Format:	Artikel
Sprache:	eng
Schlagworte:	acrolein diethyl acetal allylic substitution amphiphilic resin aryl amination aryl chlorides bond-forming reactions Catalysis Chemistry, Organic - methods cross-coupling hydrogenation metathesis mizoroki-heck reaction n-heterocyclic carbenes Organic Chemistry Phenomena organometallic Organometallic Compounds - chemistry palladium complex polymer supported Polymers reactions Review solid phase synthesis supercritical carbon-dioxide transfer transfer hydrogenation
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Beschreibung
Zusammenfassung:	Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but also aryl amination, epoxide opening, rearrangements, metathesis and cyclopropanation. Applications in the field of asymmetric synthesis are also discussed.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules15096306