Catalytic growth of carbon nanotubes with large inner diameters

Carbon nanotubes (2.4 g/g catalyst), with large inner diameters were successfully synthesized through pyrolysis of methane on a Ni-Cu-Al catalyst by adding sodium carbonate into the carbon nanotubes growth system. The inner diameter of the carbon nanotubes prepared by this method is about 20-60 nm, while their outer diameter is about 40-80 nm. Transmission electron microscopy and X-ray diffraction were employed to investigate the morphology and microstructures of the carbon nanotubes. The analyses showed that these carbon nanotubes have large inner diameters and good graphitization. The addition of sodium carbonate into the reaction system brings about a slight decrease in the methane conversion and the yield of carbon. The experimental results showed that sodium carbonate is a mildly toxic material which influenced the catalytic activity of the Ni-Cu-Al catalyst and resulted in the formation of carbon nanotubes with large inner diameters. The growth mechanism of the carbon nanotubes with large inner diameters is discussed in this paper. Uspesno su sintetizovane karbonske nanotube (2,4 g/g katalizatora) velikih unutrasnjih precnika pirolizom metana na Ni-Cu-Al katalizatoru dodatkom natrijum- karbonata u reakcioni sistem. Unutrasnji precnik nanotuba dobijenih ovom metodom bio je 20 - 60 nm, dok je spoljasnji bio 40 - 80 nm. Za ispitivanje morfologije i mikrostrukture karbonskih nanotuba koriscena je transmisiona elektronska mikroskopija i rendgenska difrakcija. Analize su pokazale velike unutrasnje precnike karbonskih nanotuba i dobru grafitizaciju. Dodatak natrijum-karbonata u reakcioni sistem smanjuje u maloj meri konverziju metana, a i prinos karbona. Eksperimentalni rezultati pokazuju da je natrijum-karbonat blagi trovac Ni-Cu-Al katalizatora i da smanjenje njegove aktivnosti dovodi do stvaranja karbonskih nanotuba vecih unutrasnjih precnika. U radu je diskutovan mehanizam rasta karbonskih nanotuba vecih unutrasnjih precnika.