Efficient Separation and Purification Method for Recovering Valuable Elements from Bismuth Telluride Refrigeration Chip Waste

Bismuth telluride and its alloys are widely utilized in thermoelectric refrigeration and power generation devices. Waste bismuth telluride-based cooling chips contain valuable elements; however, recycling processes for these materials remain underdeveloped due to their complexity. In this study, we developed a concise and efficient chemical method that does not require expensive reagents or equipment, enabling the separation and purification of tellurium, bismuth, selenium, and antimony from waste bismuth telluride-based cooling chips. Initially, the waste was leached with HCl and NaClO3 to dissolve primary elements and recover 99.9% of selenium using hydroxylamine hydrochloride. Subsequently, Na2S and NaOH were employed for precipitation and leaching, resulting in a solution containing tellurium. The precipitated residue was treated with HNO3 to oxidize antimony into insoluble SbOHN and dissolve bismuth completely. 99.8% of the bismuth telluride waste was dissolved via oxidative leaching through hydrolysis. A small amount of sodium sulfide reduced the precipitation percentage of tellurium from 11.9% to 7.5% in an alkaline solution, and the direct recovery percentage of tellurium in the form of TeO2 exceeded 90%, while the purity of TeO2 reached 99.9%. By adjusting the pH of the bismuth solution to 0.15, 98.9% of the bismuth was able to precipitate and be recovered as BiOCl, with the purity also reaching 99.9%. In summary, this study presents an efficient hydrometallurgical method for treating bismuth telluride waste and provides theoretical guidance for reagent dosage, demonstrating the significant potential for industrial applications.