Flow Injection Sensing Strategy for Determining Cationic Surfactants in Commodity and Water Samples

The formation of stable binary water-soluble sub-micellar aggregates of cetyltrimethylammonium bromide-copper-pyrocatechol violet complex (CTAB-Cu-PCV) diminishes the stability and absorbance of the Cu-PCV complex. A new flow injection spectrophotometric sensing strategy used for the determination o...

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Veröffentlicht in:Chemosensors 2022-10, Vol.10 (10), p.434
Hauptverfasser: El Hamd, Mohamed A., El-Maghrabey, Mahmoud, Abdel-Lateef, Mohamed A., Ali, Samah M., Ibrahim, Munjed M., El-Shahat, Mohamed F., Azeem, Sami M. Abdel
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Sprache:eng
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Zusammenfassung:The formation of stable binary water-soluble sub-micellar aggregates of cetyltrimethylammonium bromide-copper-pyrocatechol violet complex (CTAB-Cu-PCV) diminishes the stability and absorbance of the Cu-PCV complex. A new flow injection spectrophotometric sensing strategy used for the determination of CTAB in commodity personal care antiseptics and water samples has been established relying on the above-mentioned concept. Based on the reduction of the absorption of the Cu-PCV solution by the injection of CTAB solution at pH 6.0 and 430 nm, a linear absorbance decrease was observed over the CTAB concentration range of 2.0 to 100.0 µg mL−1 (r = 0.987). The analysis method showed limits of detection (3.3 ơ) and quantification (10 ơ) of 0.08 and 0.27 µg mL−1, respectively. The precision (RSD) for five replicate determinations was 7.9 and 3.7% at 10 and 50 µg mL−1, respectively. The developed method was applied successfully to the determination of CTAB in personal care products, namely skin lotion and vaginal wash, in addition to water samples. The corresponding RSD (n = 5) values were ≤8.2%.
ISSN:2227-9040
2227-9040
DOI:10.3390/chemosensors10100434