Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H 2 O)(CH 3 COO)(P 2 W 17 O 61 )} 2 ] 16

Reaction of the trilacunary Wells-Dawson anion {α-P W O } with Er ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H O)(CH COO)(P W O )} ] ( ). The isolated compound was structurally characterized using single crystal and powd...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2020-09, Vol.25 (18), p.4229
Hauptverfasser:	Ibrahim, Masooma, Baksi, Ananya, Peng, Yan, Al-Zeidaneen, Firas Khalil, Mbomekallé, Israël M, de Oliveira, Pedro, Anson, Christopher E
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Crystallography, X-Ray Electrochemical Techniques electrochemistry Erbium - chemistry Hydrogen-Ion Concentration lanthanide Magnetics mass spectrometry Material chemistry Molecular Conformation molecular magnetism polyoxometalates Tungsten Compounds - chemical synthesis Tungsten Compounds - chemistry
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Beschreibung
Zusammenfassung:	Reaction of the trilacunary Wells-Dawson anion {α-P W O } with Er ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H O)(CH COO)(P W O )} ] ( ). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of were investigated.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules25184229