tert-Butyl 3-(8-bromo-4H,10H-1,2-oxazolo[4,3-c][1]benzoxepin-10-yl)-2-methyl-1H-indole-1-carboxylate

In the title compound, C25H23BrN2O4, the seven-membered ring adopts a twisted-boat conformation. The indole ring system is planar within 0.021 (2) Å and the ester group [–C(=O)—O—C–] is almost coplanar with it [dihedral angle = 3.0...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (8), p.o2035-o2035
Hauptverfasser: Ankur Trigunait, P. Malathy, K. Ramachandiran, P. T. Perumal, K. Gunasekaran
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C25H23BrN2O4, the seven-membered ring adopts a twisted-boat conformation. The indole ring system is planar within 0.021 (2) Å and the ester group [–C(=O)—O—C–] is almost coplanar with it [dihedral angle = 3.0 (2)°]. The conformation of the ester group is influenced by intramolecular C—H...O interactions. In the crystal structure, molecules are linked into chains along the b axis by C—H...N hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810027297