A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

The synthesis of new trans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by 1H-N.M.R., 13C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxid...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Bioinorganic Chemistry and Applications 2010-01, Vol.2010 (1), p.238-243
Hauptverfasser: Daphnomili, Dimitra, Grammatikopoulou, Maria, Raptopoulou, Catherine, Charalambidis, George, Lazarides, Theodore, Coutsolelos, Athanasios G.
Format: Artikel
Sprache:eng
Schlagworte:
Bearing
Colleges & universities
Derivatives
Materials science
Oxidation
Photodynamic therapy
Porphyrins
Reduction
Synthesis
X-rays
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The synthesis of new trans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by 1H-N.M.R., 13C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined.
ISSN:1565-3633
1687-479X
DOI:10.1155/2010/307696