Crystal structure of dibenzylammonium hydrogen (4-aminophenyl)arsonate monohydrate
The title salt, C 14 H 16 N + ·C 6 H 7 AsNO 3 − ·H 2 O or [(C 6 H 5 CH 2 ) 2 NH 2 ][H 2 NC 6 H 4 As(OH)O 2 ]·H 2 O, ( I ), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound I crystallizes in the mono...
Gespeichert in:
| Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-11, Vol.79 (11), p.1003-1007 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The title salt, C
14
H
16
N
+
·C
6
H
7
AsNO
3
−
·H
2
O or [(C
6
H
5
CH
2
)
2
NH
2
][H
2
NC
6
H
4
As(OH)O
2
]·H
2
O, (
I
), was synthesized by mixing an aqueous solution of (4-aminophenyl)arsonic acid with an ethanolic solution of dibenzylamine at room temperature. Compound
I
crystallizes in the monoclinic
P
2
1
/c space group. The three components forming
I
are linked
via
N—H...O and O—H...O intermolecular hydrogen bonds, resulting in the propagation of an infinite zigzag chain. Additional weak interactions between neighbouring chains, such as π–π and N—H...O contacts, involving phenyl rings, –NH
2
and –As(OH)O
3
functions, and H
2
O, respectively, lead to a three-dimensional network. |
|---|---|
| ISSN: | 2056-9890 2056-9890 |
| DOI: | 10.1107/S205698902300837X |