trans -Bis(4-amino-pyridine-κ N )bis-(quin-ox-aline-2,3-di-thiol-ato-κ 2 S , S ')platinum(IV) dimethyl sulfoxide monosolvate
In the structure of the title solvated complex, [Pt(C H N S ) (C H N ) ]·C H OS or -[Pt(4- ) (qdt) ]·dmso (4- = 4-amino-pyridyl, C H N ; qdt = quinoxaline-2,3-di-thiol-ate, C H N S ; dmso = dimethyl sulfoxide, C H OS) the centrosymmetric complex exhibits Pt-S distances in agreement with other Pt -S...
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Veröffentlicht in: | IUCrData 2022-02, Vol.7 (Pt 2), p.x220101, Article x220101 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | In the structure of the title solvated complex, [Pt(C
H
N
S
)
(C
H
N
)
]·C
H
OS or
-[Pt(4-
)
(qdt)
]·dmso (4-
= 4-amino-pyridyl, C
H
N
; qdt = quinoxaline-2,3-di-thiol-ate, C
H
N
S
; dmso = dimethyl sulfoxide, C
H
OS) the centrosymmetric complex exhibits Pt-S distances in agreement with other Pt
-S bond lengths found in platinum(IV) di-thiol-ene complexes. The qdt ligands have inter-molecular inter-actions with an amine hydrogen atom on a 4-
ligand (hydrogen bonding) and have sandwich π-π inter-actions with a neighboring qdt ligand. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314622001018 |