2-{[2-(1-Methyl-2,2-dioxo-3,4-dihydro-1H-2λ(6),1-benzothia-zin-4-yl-idene)hydrazin-1-yl-idene]meth-yl}phenol
In the title compound, C(16)H(15)N(3)O(3)S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N-N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) Å from the mean plane of the other five atoms (r.m.s....
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (Pt 9), p.o2643-o2643 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title compound, C(16)H(15)N(3)O(3)S, the dihedral angle between the aromatic rings is 8.18 (11)° and the C=N-N=C torsion angle is 178.59 (14)°. The conformation of the thia-zine ring is an envelope, with the S atom displaced by 0.8157 (18) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.045 Å). An intra-molecular O-H⋯N hydrogen bond closes an S(6) ring. In the crystal, weak C-H⋯O inter-actions link the mol-ecules, with all three O atoms acting as acceptors. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812034101 |