Aqueous thermogalvanic cells with a high Seebeck coefficient for low-grade heat harvest

Thermogalvanic cells offer a cheap, flexible and scalable route for directly converting heat into electricity. However, achieving a high output voltage and power performance simultaneously from low-grade thermal energy remains challenging. Here, we introduce strong chaotropic cations (guanidinium) and highly soluble amide derivatives (urea) into aqueous ferri/ferrocyanide ([Fe(CN) 6 ] 4− /[Fe(CN) 6 ] 3− ) electrolytes to significantly boost their thermopowers. The corresponding Seebeck coefficient and temperature-insensitive power density simultaneously increase from 1.4 to 4.2 mV K −1 and from 0.4 to 1.1 mW K −2 m −2 , respectively. The results reveal that guanidinium and urea synergistically enlarge the entropy difference of the redox couple and significantly increase the Seebeck effect. As a demonstration, we design a prototype module that generates a high open-circuit voltage of 3.4 V at a small temperature difference of 18 K. This thermogalvanic cell system, which features high Seebeck coefficient and low cost, holds promise for the efficient harvest of low-grade thermal energy. Achieving high thermopower in liquid-state thermogalvanic cells is vital to realize a low-cost technology solution for thermal-to-electrical energy conversion. Here, the authors present aqueous thermogalvanic cells based on modified electrolyte with enhanced Seebeck coefficient and thermopower.