Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System

Palladium-Catalysed Intramolecular C–N versus C–C Coupling: The Effect of 1,8-peri-Interaction in the Naphthalene System

Abstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8- peri -interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides su...

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Veröffentlicht in:SynOpen (2017) 2019-01, Vol.3 (1), p.11-15
Hauptverfasser: Debnath, Sudarshan, Mondal, Shovan
Format: Artikel
Sprache:eng
Schlagworte:
1,8-peri-interaction
cyclization
fused-ring
heterocycles
naphthalene
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Zusammenfassung:Abstract Palladium-catalysed competitive intramolecular C–N and C–C coupling of 2-amino-2′-bromodiarylsulfones has been carried out based on 1,8- peri -interactions for the synthesis of phenothiazinedioxide and benzonaphthathiophenedioxide derivatives. A DFT study has been performed that provides support for the influence of the 1,8- peri -interaction.
ISSN:2509-9396
2509-9396
DOI:10.1055/s-0037-1611667