Synthesis and Some Physical Properties of a New Series of Layered Selenides (LnO)CuSe (Ln=Lanthanides)

A new series of layered selenides (LnO)CuSe (Ln=La, Ce, Nd, Sm, Gd, Tb, Dy, Ho, Y) with (LaO)AgS-type structure was prepared. All the compounds were semiconductors. Magnetic susceptibility measurements revealed that the lanthanide ions are in the trivalent state and the values of Weiss temperature θ...

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Veröffentlicht in:Japanese Journal of Applied Physics 1993-01, Vol.32 (S3), p.316
Hauptverfasser: Ohtani, Tsukio, Hirose, Masatomo, Sato, Tatsuya, Nagaoka, Kazuhiro, Iwabe, Makoto
Format: Artikel
Sprache:eng
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Zusammenfassung:A new series of layered selenides (LnO)CuSe (Ln=La, Ce, Nd, Sm, Gd, Tb, Dy, Ho, Y) with (LaO)AgS-type structure was prepared. All the compounds were semiconductors. Magnetic susceptibility measurements revealed that the lanthanide ions are in the trivalent state and the values of Weiss temperature θ lie within ±15 K for all the compounds. The preparation and the electrical resistivity of (LaO)Cu(S 1- x Se x ) (0≤ x ≤1) and (La 1- x Sr x )OCuSe (0≤ x ≤0.2) systems are also reported.
ISSN:0021-4922
1347-4065
DOI:10.7567/JJAPS.32S3.316