EXAFS and XANES Investigation of the Structure of TiCl 4 and TiCl 4 -Filodiene Reaction Intermediates in Solution

EXAFS and XANES Investigation of the Structure of TiCl 4 and TiCl 4 -Filodiene Reaction Intermediates in Solution

The local structure around TiCl 4 and TiCl 4 - -Filodiene compexes in solution has been studied by means of x-ray absorption spectroscopy. Analysis of the EXAFS spectra shows that TiCl 4 coordinate to two oxygen atoms belonging to the organic counterpart Theoretical XANES spectra have been calculate...

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Veröffentlicht in:Japanese Journal of Applied Physics 1993-01, Vol.32 (S2), p.514
Hauptverfasser: Sanchez, M. Concepción, Garcia, Joaquín, Mayoral, Jose Antonio, Proietti, M. Grazia, Chaboy, Jesus, Ruiz-Lopez, Manuel. F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The local structure around TiCl 4 and TiCl 4 - -Filodiene compexes in solution has been studied by means of x-ray absorption spectroscopy. Analysis of the EXAFS spectra shows that TiCl 4 coordinate to two oxygen atoms belonging to the organic counterpart Theoretical XANES spectra have been calculated and compared with the experimental data and the features present in the spectra interpreted in terms of multiple scattering contributions.
ISSN:0021-4922
1347-4065
DOI:10.7567/JJAPS.32S2.514